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Pumping up ethanol production

OTTAWA — For years, critics argued that using corn to make ethanol fuel would set off an agricultural food crisis. They feared the conventional method would mean not enough cobs to feed both our cars and our stomachs. But with new research on ethanol technology in Canada, companies are showing that the alternative fuel can be made in more ways than one. This could mean that we’ll never suffer from the dreaded popcorn famine, or an ethanol drought.


On the south end of Ottawa lies a demonstration facility that makes ethanol in an unconventional way. It’s operated by Iogen Corporation, one of the nation’s biotechnology firms, whose slogan salutes ethanol as the clean-burning fuel of the future. There are high hopes that the fuel will help to curb both our gasoline cravings and greenhouse gas emissions (GHGs).

Iogen’s research manager, Heather Pikor, sits down in the boardroom to discuss the innovative process and technology, which was over 20 years in the making. She’s brought in a number of small jars. The first contains what appears to be chopped up straw, similar to what you’d find on a barn floor. The contents of the very last, clear and almost water-like, is ethanol.

" No one else uses enzymes to make ethanol" says Pikor. "There are no other companies making cellulose ethanol right now."

A view of cellulose technology at Iogen's plant in Ottawa

The privately owned company runs the world’s only demonstration plant that makes cellulose ethanol, using enzyme technology from agricultural waste like corn stover, barley, and cereal straws.

Right now, they supply a handful of pumps in Ottawa and can process up to 20 to 30 tonnes of straw per week. Today, all vehicles can burn up to 10 per cent of ethanol mixed with unleaded gasoline (E10 blend) without any engine modification.

Pikor says that the problem is fuel production. We have the cars and infrastructure to use ethanol, but there simply isn’t enough of it.

Currently, Iogen is working to perfect their process before selling it worldwide. A move to commercializing its technology could mean more of this clean-burning fuel.

The unconventional process

Iogen’s novel process begins by adding leftover stover and straw into a pipe where it's chopped up as if in a blender. It goes through a high-temperature acidic cook where it’s stewed like a pot of vegetables. As the fibre becomes soft, all of its sugars are liberated.

Enzymes, which are non-living proteins, are added to the mix to help in the chemical reactions. The enzymes occur naturally in a fungus called Trichoderma reesei, which Iogen grows in sterile fermenters. After its moves through a natural life cycle of about one week, it oozes enzymes that are pumped into the pipe. The enzymes break down the cooked fibre into the familiar liquid sugar, glucose.

The chemical breakdown takes a few days. Eventually all that’s left is a mixture of half liquid glucose and another half, a solid-fibre called lignin. Iogen separates the two and adds

yeast to the liquid sugar, which then ferments into alcohol. The alcohol is distilled to remove the water, leaving only the purest form of ethanol. It’s then sold to the pumps and used to make our engines run while releasing the least amount of GHG emissions.

The large-scale process involves energy heat integration, water recycling and the use of by-products like lignin to fuel it.

The leftover lignin is a crucial by-product of the process. The fibre is fed into specially made turbines, designed to burn it. Instead of importing energy to fuel the machines (causing more GHGs), lignin fires up the process again.

Iogen hopes to boost production by commercializing this enzyme technology. They have already received worldwide recognition because they’ve shown in the plant that it works.

Still, Iogen is perfecting the process. Pikor says they hope to build the first plant by 2007 and each could cost upwards of $400 million. Leading car and oil companies like Volkswagen and Shell have shown interest, by announcing partnerships to build plants as far away as Germany.

But Iogen may not be Canada’s only success story. Other companies are also trying to stir ethanol’s production pot. By offering a faster process, B.C.’s Syntec Biofuel, shows that there could be better methods out there.

Syntec has also refined the conventional ethanol-making method in its five years of research. Lawrence Wong, the principal founder of the company, says its process is unique and different from Iogen’s.

“Our process is shorter because it has fewer steps. We don’t have a fermentation stage, which can take days. We make ethanol thousands of times faster. We can produce it in a matter of seconds,” he says.

Making ethanol from syngas

Syntec is also not just restricted to making ethanol out of agricultural waste.

The company can produce ethanol iusing gas from burning landfill, manure, sewage and wood. For example, Syntec’s process involves taking sewage and burning it in a chamber to make gas. It’s then purified through a filter to remove contaminants like carbon dioxide and nitrogen. The burning produces only five per cent waste. The ash and char can be used for other things, like agricultural fertilizer.

Next, the gas is reformed into a mixture of hydrogen and carbon monoxide called syngas. After it’s compressed, special patented catalysts are added to turn it into ethanol.

Syntec’s catalysts are multi-metal solids, which are the driving forces behind the process. The heat released in the method creates enough thermal energy to start it again like lignin does in Iogen’s plant.

Wong says Syntec already has two patents on its catalysts. He predicts that the process will be ready in the next two or three years.

" Nothing is new about the process except Syntec’s catalysts. It will be very easy to commercialize because syngas technology already exists, it’s been used for years and it works."

MacEwen, Mr. Gas, Sunoco, Suny's, Francis Fuels and Drummond gas stations all sell ethanol blended fuel.

Wong is hopeful that Syntec’s technology will change the ethanol industry because of its low operating costs and quick production rates. With its innovative technology, production may never be an issue he says.

Currently, Canada is a net importer of ethanol, says Claude Robert, a senior economist at the Office of Energy Efficiency at National Resources Canada.

" We produce about 200 million litres of ethanol a year, but we import about 125 million litres from the United States," he says.

Will new technologies pump ethanol production?

The Canadian government is trying to encourage more production, Robert explains. Under its $100 million Ethanol Expansion Program of 2003, it has given financial assistance to build five conventional plants in Canada.

'Research and development funding for ethanol technology gets less than biodiesel and hydrogen.They get only about $750, 000 to $1 million a year which is low. It’s enough to support about five companies.'

Robert says the government is also very interested in new technology like Iogen’s cellulosic process and have discussed with Iogen, new sites for a commercial plant in places like Saskatchewan. He cites the government’s interest in new development companies like Syntec too. It's important in the country’s quest for more ethanol production and use.

Bill Cruickshank, manager of Biochemical Conversion at Natural Resources Canada says it takes awhile before new technology is commercialized to start production.

The funding for Iogen’s research was spread out over a number of years, and right now government funding isn’t that high, he says.

"Research and development funding for ethanol technology gets less than biodiesel and hydrogen," he says. "They get only about $750, 000 to $1 million a year which is low. It’s enough to support about five companies."

Wong says Syntec gets about $200,000 a year. Pikor cites Canadian government support for Iogen’s research over many year including a $10 million loan to build the demonstration plant. Both companies also get money from private organizations and venture capitalists.

Syntec’s methods are fast, but Cruickshank says it could take a long time before companies like it, can start building commercial plants like Iogen is going to do.

"Iogen’s technology is advanced in terms of maturity because it started researching years ago," he says. "They are close to commercialization where other companies like Syntec may not be at that stage yet. The time and money it takes to reach that point and build a demonstration plant and test it out, takes five, 10, 15 and in Iogen’s case, 20 years."

Whether or not these new technologies will really live up to their production promise isn't known, Cruickshank explains. He says new technology is always more expensive and so it’s harder for it to be competitive.

Ethanol could become cost-competitive with government financial assistance and if oil prices remain high.

"It’s like when new DVD or CD players first came out it was $1000, now it’s half the price. The price of new technology eventually always goes down,” he says. "Cellulose ethanol or Syntec’s technology will be expensive in the beginning and so will its ethanol because it’s more costly to produce."

Cruickshank explains that we may need some government financial assistance to build and operate new ethanol plants for it to be cost-competitive.

"By the time the fifth or sixth plant is built, the price of the technology and operating it will go down. And if the price of oil stays high, then ethanol can compete. Companies will start buying more ethanol to blend and make their fuel."

Related Links

Canadian Renewable Fuels Association: Ethanol Reducing Greenhouse Gas Emissions

Natural Resources Canada: Canada's Ethanol Expansion Program

Ethanol Producer Magazine: Everything you need to know about the about ethanol

Ethanol for
our vehicles

All car engines built since the 1970s can burn up to 10 percent ethanol (E10) in fuel mixtures. All manufacturers approve the use of E10 blends and warrant their vehicles for this fuel.

We can use ethanol in much higher proportions - up to 85 percent ethanol and 15 percent gasoline (E85) - in special factory-made vehicles. There are a limited but growing number of E85 vehicles being made by auto manufacturers to test market demand for ethanol. They can run on straight gasoline or on any proportion of ethanol mixed with gasoline, up to the 85 percent limit.

Source: Natural Resources Canada

 

The smog reducer

Ethanol contains 35% oxygen. Adding oxygen to fuel results in more complete fuel combustion reducing harmful tailpipe emissions.

Ethanol can play a big role in helping Canada meet its climate change goals. On a full cycle basis, using a litre of E10 fuel instead of straight gasoline can reduce greenhouse gas emissions by 3 to 4 percent if it is made from grain. If made from cellulose it can be reduced by 6 to 8 percent. Using E85 fuel instead of straight gasoline can reduce net emissions by as much as 75 percent.

"The Canadian government estimates If 35 percent of gasoline in Canada contained ten percent ethanol, GHG emissions would be reduced by 1.8 megatonnes per year (1.8 million tonnes), the equivalent of removing more than 400,000 vehicles from the road

Source: Canadian Renewable Fuels Association and Natural Resources Canada

 



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